You sure can.
To add new card details stored by the payment protection provider, simply click on ‘Add New Card’ when making a card payment. This will allow you to add the new payment details by completing a new form.
Should you wish to remove an existing card you can do this when making a card payment by selecting the appropriate card you wish to remove and clicking on "Remove Payment Method".
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Whenever shopping on any online website or viewing online banking statements, it is important to remember that any details provided on a webpage that starts with HTTPS are sent via an encrypted and secure network.